How do I make Heroku recongise Procfile on the app/website?

Okay after many issues with Heroku, I have narrowed it down to it not reconsigning my Procfile, when I go onto my account and run bash then ls this comes up: I'm running lastest Groovy Gorilla and Python 3.9.

directory      index.php         Me         requirements.txt
composer.json  myapp             Project    runtime.txt
db.sqlite3     manage.py         projects   venv

Then I ran heroku ps this came up:

 Warning: heroku update available from 7.56.0 to 7.56.1.
Free dyno hours quota remaining this month: 548h 30m (99%)
Free dyno usage for this app: 1h 29m (0%)
For more information on dyno sleeping and how to upgrade, see:
https://devcenter.heroku.com/articles/dyno-sleeping

No dynos on myapp

Here's my Procfile: on Pycharm-name Procfile

  web: gunicorn.Project.wsgi

Its connected to github and possibly CLI

The requirements.txt:

asgiref==3.4.1
boto3==1.18.5
botocore==1.21.5
certifi==2021.5.30
charset-normalizer==2.0.3
click==8.0.1
dj-database-url==0.5.0
Django==3.2.5
django-heroku==0.3.1
gunicorn==20.1.0
idna==3.2
Pillow==8.3.0
psycopg2==2.9.1
pytz==2021.1
requests==2.26.0
sqlparse==0.4.1
urllib3==1.26.6
whitenoise==5.3.0

How do I make it recongise Procfile? I'm really don't know what to do.