Before updating a software which canonical does not support for updates (like vlc, Skype), do I need to add the relevant ppa to the system before run "apt-get install packagename" or "apt-get --only upgrade install packagename" ? (I'm using ubuntu 13.10)
If I understand your question correctly the answer is
No.
The Ubuntu repositories contain both VLC and Skype, but you might be able to get newer versions from a PPA.
One way to tell if the package you want is in your current repos (including any PPAs you've already added) is:
Or you can open the software center and search. PPAs are only for software that isn't already in the repos.
For software are not available in Ubuntu repository Yes, You have to add APP before updating list, then try to install software related to APP.