When I wanted to save TIFF file, I got this message box:
TIFF save cannot handle indexed images with alpha channel
Although I had no alpha layer.
Here is an example which cannot be exported to TIFF file because of a not-existing alpha channel
It seems to be a bug - I do not know - the only remedy is:
Ebene/Ebene auf Bildgröße and export as TIFF afterwards.
If this doesn't work:
then try:
Go to layers --> Transparency --> remove alfa channel then export your image.