I have a Postfix server that is having issues receiving a distribution email from a customer mail server that has over 100+ recipients. I have increased debug information using debug_peer_level and debug_peer_list.
What I have found is that after the Postfix server receives 99-102 "RCPT TO:" SMTP commands, it closes the connection.
The logs don't really indicate exactly what Postfix is doing at that point and I have increased my debug_peer_level to 99 to make sure I'm not missing any additional information.
Increase the recipient limit with
Add this line to your main.cf and then, reload postfix.