How can I donate older, unused or surplus computers? What facilities or organizations exist? Can I ship equipment to them? Is it tax deductible? I'd like them to go directly into educational or low-income use, rather than being recycled for scrap metals.
A couple of ideas:
Here in Portland, you can drop them off at Free Geek, who then sends off the usuable bits and pieces to recyclers, and the stuff that works is reformatted and resold to the community as low-cost Ubuntu boxes. The project is interesting because those folks that can't afford much can still get a computer by working in the recycling center for a period of time (I think it's 24 hours of service), after which they get a "Geekbox", typically a P3 or P4 with the aforementioned-Ubuntu install on it, for free. Generally speaking, it has to be really really old (Pentium-2 generation) or completely broken to end up as recycled.
I would put in a search term for community computer recycling for your area and see what comes up.
If they are truly obsolete, don't. Nobody wants your old junk, and groups that think they do have no clue in 98.5% of situations. Especially if you're disposing of CRT monitors.
Several reasons for this:
My advice - pay the $25-40 to dispose of the device properly, and factor that cost into the TCO of your server environment. Or lease equipment from major vendors and make it their problem. Help organizations you care about with cash, labor or durable goods.
Have a look at Computers with Causes.
If you're near Texas, drop them off at The Helios Initiative. Kenneth Starks and his voluteers are doing excellent work in fixing them and donating them (with free internet access) to poor families who's children need computers for educational use but who cannot afford a computer, let alone internet access. And the computers really are for the children and not for their parents.
For example: http://www.computers4africa.org.uk/
You can try getting in touch with local towns, cities and municipalities. Sometimes programs are in place for just this purpose.