This registers seven new mail transmission types (ESMTPA, ESMTPS,
ESMTPSA, LMTP, LMTPA, LMTPS, LMTPSA) for use in the "with" clause of
a Received header in an Internet message.
...
The new keyword "ESMTPS" indicates the use of ESMTP when STARTTLS
is also successfully negotiated to provide a strong transport
encryption layer.
How about RFC3848