I've two UPSs. I'm going to connect two devices to them and the combined wattage of the devices is below the rating for each single UPS. Would it be better* to connect the UPS device in serial with both devices connected, or to connect one device to each UPS separately?
Edit: *where better means the devices will remain powered up for longer during a power failure.
Neither.
Just use one UPS unless you have a specific battery runtime requirement, dual power supplies on both devices or want the added complexity of managing two UPS units.
Your other option is to but a battery with the runtime you actually need. It's quite easy to spec a solution that will run for 4 hours or more. You probably don't need that :)
See: Automatic power on after graceful shutdown on UPS
Please don't go down the path of connecting your UPS units in series (or daisy-chaining them). It's not a good solution.
See here:
No, you can't and shouldn't daisy chain (or serialise) a UPS by plugging in another UPS. Run them side by side (in parallel as I think you're calling it) and make them power completely different devices/servers.
Or, better still, buy a much larger capacity UPS.
I quote the APC website which sums up the reasons why not beautifully.