When using an email address in /etc/audit/auditd.conf, there is an option verify_email which is defined as,
This option determines if the email address given in action_mail_acct is checked to see if the domain name can be resolved. This option must be given before action_mail_acct or the default value of yes will be used.
When is the actual check performed? For example, when the service is started? When an audit event occures?